Some Comments on Fulminic Acid (Knallsäure) and a Praise toHeinrich Wielandand his Work on Organic Derivatives of Nitrogen
| Autor: | Peter Swoboda, Wolfgang Beck, Gerd Fischer |
|---|---|
| Rok vydání: | 2017 |
| Předmět: |
Sodium
Fulminic acid chemistry.chemical_element Sulfuric acid 010402 general chemistry 01 natural sciences Nitrogen Cycloaddition 0104 chemical sciences Adduct Inorganic Chemistry chemistry.chemical_compound chemistry Polymerization 0103 physical sciences Polymer chemistry Mass spectrum Organic chemistry 010303 astronomy & astrophysics |
| Zdroj: | Zeitschrift für anorganische und allgemeine Chemie. 643:353-356 |
| ISSN: | 0044-2313 |
| DOI: | 10.1002/zaac.201600463 |
| Popis: | The structure, vibrational spectrum, the polymerization and [3+2] cycoaddition reactions of fulminic acid are discussed. In the mass spectra of the solid deposit from gaseous fulminic acid (prepared from sodium fulminate and sulfuric acid) the mass of the adduct of HCNO with hydrogen cyanide was detected, which may be formed by Huisgen 1,3-dipolar cycloaddition. As examples for Heinrich Wieland's experimental mastership the polymerization and his syntheses of fulminic acid and of explosive dinitrosomethanide [HC(NO)(2)](-) are emphasized;the structure of the latter has recently been disclosed by X-ray structure determination. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Plný text