Photocatalytic Generation of π-Allyltitanium Complexes from Butadiene via a Radical Strategy

Autor:	Shuangjie Lin, Xi-yu Li, Lei Shi, Fusheng Li
Rok vydání:	2021
Předmět:	Chemistry Organic Chemistry Rapid access Photocatalysis Fine chemical Raw material Combinatorial chemistry Catalysis
Zdroj:	Synthesis. 53:1889-1900
ISSN:	1437-210X 0039-7881
DOI:	10.1055/s-0040-1706024
Popis:	The direct conversion of industrial feedstock chemicals into highly valuable fine chemical intermediates is of great appeal to the synthetic community as well as industrial applications. This study reports a conceptually new radical strategy for the photocatalytic generation of π-allyltitanium complexes from butadiene. This novel and environmentally benign strategy enables the direct three-component allylation of carbonyls with 1,3-butadiene and α-bromocarboxylates, providing rapid access to valuable homoallylic alcohols with exceptional regio- and diastereoselectivity control.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::a2a0a0ea0bbd79af9179095ad5e71afe https://doi.org/10.1055/s-0040-1706024 Zobrazit plný text záznamu