The mass spectra of phenothiaphosphine derivatives

Autor:	Itshak Granoth, Z. Pelah, E. D. Bergmann, A. Kalir
Rok vydání:	1970
Předmět:	Chemistry Stereochemistry Aryl Polyatomic ion Aromaticity Biochemistry Medicinal chemistry chemistry.chemical_compound Fragmentation (mass spectrometry) Phosphorus atom Mass spectrum Molecular Medicine Instrumentation Spectroscopy Phosphine
Zdroj:	Organic Mass Spectrometry. 3:1359-1364
ISSN:	1096-9888 0030-493X
DOI:	10.1002/oms.1210031103
Popis:	The molecular ion of the phenothiaphosphine derivatives is fairly stable. Under electronimpact, the phenothiaphosphines (I) and phenothiaphosphinic acids (IV, R = H) undergo a one-step elimination of the phosphorus atom together with the groups attached to it. Substitutents in the aromatic rings, as well as on the phosphorus, influence the fragmentation pattern; ring methyl, e.g. leads to tropylium structures. Phosphine oxides of type V lose RO˙, probably after a rearrangement, when R = aryl, but R˙ if it is methyl.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::a28dc23870fdd6e1fcfeff4e30c16a9c https://doi.org/10.1002/oms.1210031103 Zobrazit plný text záznamu Plný text