Radical polymerization of methyl methacrylate in the presence of sulphuric acid

Autor:	V.P. Zubov, B.M. Abu el'Khair, M. B. Lachinov, Victor A. Kabanov
Rok vydání:	1975
Předmět:	Nitroxide mediated radical polymerization Living free-radical polymerization Chain-growth polymerization Cobalt-mediated radical polymerization Bulk polymerization Polymerization Chemistry Polymer chemistry Radical polymerization General Engineering Ionic polymerization Photochemistry
Zdroj:	Polymer Science U.S.S.R.. 17:954-959
ISSN:	0032-3950
Popis:	A study was made of the mechanism of MMA polymerization in the presence of 80 and 95.6% H2SO4 with a 1 : 1 molar ratio of [H2SO4]/[MMA]. The reaction was initiated by UV irradiation at 20°. It was found that the reaction can be described in terms of ordinary addition radical polymerization. The main kinetic effect in the studied systems is a reduction in rate of bimolecular termination.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::a26cbbcaf29804398081fcc721b02070 https://doi.org/10.1016/0032-3950(75)90269-5 Zobrazit plný text záznamu