Ni-B catalyst with metal modifiers for partial hydrogenation of fatty acid methyl esters at mild conditions
| Autor: | Guangtao Wei, Zongwu Xin, Zhongmin Li, Ruilin Mo, Linye Zhang, Lei Gao |
|---|---|
| Rok vydání: | 2021 |
| Předmět: |
chemistry.chemical_classification
010405 organic chemistry Fatty acid General Chemistry 010402 general chemistry 01 natural sciences 0104 chemical sciences Catalysis Partial hydrogenation Metal chemistry Chemical engineering visual_art Specific surface area Chemical reduction visual_art.visual_art_medium Small particles Alloy catalyst |
| Zdroj: | Journal of Chemical Sciences. 133 |
| ISSN: | 0973-7103 0974-3626 |
| DOI: | 10.1007/s12039-021-01930-5 |
| Popis: | A low-cost Ni-B alloy catalyst was prepared by chemical reduction method and used for partial hydrogenation of fatty acid methyl esters. The conditions for catalyst preparation, including Ni to B ratio, pH of NaBH4 solution, types and quantity of metal modifiers were optimized. Ni-La-B, prepared by modification of Ni-B with La, showed significantly high catalytic partial hydrogenation activity. The optimum textural properties (small particle size, high specific surface area and well-defined pore structure) and electron enrichment of active Ni sites were the favorable factors for the high hydrogenation activity of Ni-La-B catalyst, which showed reasonable stability in catalyst recycle experiments. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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