Abraham model enthalpy of solvation correlations for solutes dissolved in 1-alkanol solvents (C4–C6)

Autor:	Heidi Zettl, William E. Acree, Erin Hart, Damini Grover, Michael H. Abraham
Rok vydání:	2015
Předmět:	Training set Chemistry Test set Enthalpy Materials Chemistry Solvation Experimental data Physical chemistry Thermodynamics Physical and Theoretical Chemistry Condensed Matter Physics Standard deviation Electronic Optical and Magnetic Materials
Zdroj:	Physics and Chemistry of Liquids. 53:638-659
ISSN:	1029-0451 0031-9104
DOI:	10.1080/00319104.2015.1018259
Popis:	Experimental data have been compiled from the published literature pertaining to enthalpies of solvation of inorganic gases and organic solutes dissolved in 1-butanol, 1-pentanol and 1-hexanol at 298 K. It is shown that the Abraham model can be used to satisfactorily correlate the measured enthalpies of solvation in 1-butanol, 1-pentanol and 1-hexanol to within standard deviations of 2.86 kJ/mole for 131 data points, 2.67 kJ/mole for 92 data points and 2.89 kJ/mole for 84 data points, respectively. The derived equations were validated by training set and test set analyses.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::a24ddba7581cef3372d2e6c7be12459e https://doi.org/10.1080/00319104.2015.1018259 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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