The Remote Activation of Chemical Bondsvia Metal Coordination

Autor:	Huazhi Li, Eric J. Watson, Moonhyun Oh, Dwight A. Sweigart, Gene B. Carpenter, Kunquan Yu
Rok vydání:	2003
Předmět:	Indole test chemistry.chemical_compound chemistry Chemical bond Nucleophile Transition metal Thiophene Benzothiophene General Chemistry Biphenylene Ring (chemistry) Photochemistry Medicinal chemistry
Zdroj:	Advanced Synthesis & Catalysis. 345:1053-1060
ISSN:	1615-4169 1615-4150
DOI:	10.1002/adsc.200303080
Popis:	The activation of chemical bonds to cleav- age by mild metal nucleophiles can be achieved by precoordination of a transition metal fragment to a site remote from the bond in question. The following bonds have been activated in this manner by 6 - coordination to an internal arene ring: C Ci n biphenylene, CS in benzothiophene and dibenzo- thiophene, CSe in benzoselenophene, CO in ben- zofuran, and NH in indole.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::a24b5b5783fc6de6cb5c516b321b910d https://doi.org/10.1002/adsc.200303080 Zobrazit plný text záznamu Plný text