Optimisation of CISCuT cell design
| Autor: | V Groen-Smit, J Penndorf, Stefaan Degrave, J Wienke, Marc Burgelman |
|---|---|
| Rok vydání: | 2001 |
| Předmět: |
business.industry
Chemistry Band gap Doping Metals and Alloys Mineralogy Surfaces and Interfaces Cell design Buffer (optical fiber) Surfaces Coatings and Films Electronic Optical and Magnetic Materials law.invention Copper sulfide chemistry.chemical_compound Tunnel junction law Solar cell Materials Chemistry Optoelectronics business Sheet resistance |
| Zdroj: | Thin Solid Films. 387:165-168 |
| ISSN: | 0040-6090 |
| DOI: | 10.1016/s0040-6090(00)01811-3 |
| Popis: | The special features of the CISCuT material require cell concepts that differ from conventional CuInS2 solar cells. For the n-type CISCuT bulk material, a p-type buffer is required. In this paper, the currently used p-type Cu(O,S) buffer layer is replaced by the higher bandgap material CuI. On 10-mm2 cells the efficiency profit made by the replacement of Cu(O,S) with CuI is demonstrated. For larger cell areas, two different cell configurations are described. In the first concept, a ZnO:Al window layer is deposited on top of the CuI buffer layer. The second concept uses a metal grid as a front contact. Theoretical considerations point out the consequences of the given concepts for the CISCuT cell performance. For the Cu/CISCuT/CuI/ZnO:Al layer configuration, an additional tunnel junction is expected at the interface between the p-type CuI and the n-type ZnO:Al. In the metal grid concept, CuI doping with iodine is required to lower the sheet resistance of the layer. Some precautions against iodine out-diffusion have to be taken. For the window layer configuration on an area of 400 mm2, a cell performance of 5.2% was obtained. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Full Text from ScienceDirect