A {Na2Fe10} isobutyrate cluster, interlinked into 1D chains

Autor:	Paul Kögerler, Jan van Leusen, Victor Ch. Kravtsov, Daniel Podgornii, Svetlana G. Baca
Rok vydání:	2021
Předmět:	010405 organic chemistry Chemistry Shell (structure) General Chemistry 010402 general chemistry Condensed Matter Physics 01 natural sciences 0104 chemical sciences Crystallography chemistry.chemical_compound Cluster (physics) Sodium azide General Materials Science Acetonitrile
Zdroj:	CrystEngComm. 23:5153-5156
ISSN:	1466-8033
DOI:	10.1039/d1ce00777g
Popis:	Charge-neutral [Na2Fe10O6(OH)4(isobutyrate)14(MeO)2(MeCN)2] coordination clusters, comprising a hollow ‘Chinese lantern’-like shell of six condensed planar triangular {FeIII3(μ3-O)} motifs, form upon ultrasonication of trinuclear Fe(III) isobutyrate units in acetonitrile in the presence of sodium azide and 4,4′-bipyridine (bpy), resulting in {[Na2Fe10O6(OH)4(isobutyrate)14(bpy)(MeO)2(MeCN)2]·MeOH}n in which the dodecanuclear cluster units are bpy-bridged into 1D chains.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::a2327a3fb88b4a6424281af637454ba6 https://doi.org/10.1039/d1ce00777g Zobrazit plný text záznamu