Spectrochemical analysis of the laser-induced nitration of three cycloalkanes

Autor:	Ann E. Stanley, Larry M. Ludwick, Judith M. Bonicamp, Susan E. Godbey
Rok vydání:	1993
Předmět:	chemistry.chemical_classification chemistry.chemical_compound Cycloalkane Hydrocarbon chemistry General Engineering Infrared spectroscopy Fourier transform infrared spectroscopy Cyclopentane Spectroscopy Photochemistry Cyclopropane Cyclobutane
Zdroj:	Spectrochimica Acta Part A: Molecular Spectroscopy. 49:1987-1998
ISSN:	0584-8539
DOI:	10.1016/s0584-8539(09)91010-8
Popis:	The tunable continuous wave carbon dioxide laser-induced reactions of cyclopropane, cyclobutane and cyclopentane with NO 2 have been carried out under a variety of reaction conditions. Presented herein is our qualitative Fourier transform infrared spectroscopy and gas chromatography—mass spectroscopy spectrochemical analysis of the product mixtures. Optimal conditions were found for producing nitrocycloalkanes while reducing or eliminating the production of undesirable products. The array of products was found to be highly sensitive to the specific reaction conditions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::a22ffa1df40ebbf954db4cc02e015c56 https://doi.org/10.1016/s0584-8539(09)91010-8 Zobrazit plný text záznamu