Trimythyllead chloride dissociation in aqueous and methanolic solutions

Autor:	Peter R. Wells, Vittorio Lucchini
Rok vydání:	1980
Předmět:	Aqueous solution Chemistry Dimer Chemical shift Organic Chemistry Inorganic chemistry Biochemistry Chloride Dissociation (chemistry) Inorganic Chemistry Dissociation constant chemistry.chemical_compound Materials Chemistry medicine Methanol Physical and Theoretical Chemistry medicine.drug
Zdroj:	Journal of Organometallic Chemistry. 199:217-222
ISSN:	0022-328X
DOI:	10.1016/s0022-328x(00)83854-1
Popis:	The dissociation constants of (CH3)3PbCl at 26°C in water and in methanol have been determined to be 0.51 mol/l and 4.65 x 10 -4 mol/l, respectively, from the variations of Pb NMR chemical shifts (by INDOR) with concentration. Chemical shifts to (CH3)4Pb have been obtained for (CH3)3PbCl, for solvated (CH3)3Pb+, and for a possible dimer [(CH3)3PbCl]2 formed in methanol.
Databáze:	OpenAIRE
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