Kinetics of the gas-phase reaction of hydroxyl with nitryl chloride from 259 to 348 K
Autor: | M. J. Ezell, H. N. Berko, Barbara J. Finlayson-Pitts, J. A. Ganske |
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Rok vydání: | 1992 |
Předmět: | |
Zdroj: | The Journal of Physical Chemistry. 96:2568-2572 |
ISSN: | 1541-5740 0022-3654 |
DOI: | 10.1021/j100185a032 |
Popis: | The temperature dependence of the rate constant for the gas-phase reaction of OH with ClNO 2 has been determined from 259 to 348 K using a fast flow discharge system. The decay of OH was followed using resonance fluorescence in the presence of a great excess of ClNO 2 . Two different flow tube wall coatings, phosphoric acid and halocarbon wax, were used to check for possible heterogeneous reactions |
Databáze: | OpenAIRE |
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