Kinetics of the gas-phase reaction of hydroxyl with nitryl chloride from 259 to 348 K

Autor: M. J. Ezell, H. N. Berko, Barbara J. Finlayson-Pitts, J. A. Ganske
Rok vydání: 1992
Předmět:
Zdroj: The Journal of Physical Chemistry. 96:2568-2572
ISSN: 1541-5740
0022-3654
DOI: 10.1021/j100185a032
Popis: The temperature dependence of the rate constant for the gas-phase reaction of OH with ClNO 2 has been determined from 259 to 348 K using a fast flow discharge system. The decay of OH was followed using resonance fluorescence in the presence of a great excess of ClNO 2 . Two different flow tube wall coatings, phosphoric acid and halocarbon wax, were used to check for possible heterogeneous reactions
Databáze: OpenAIRE