A Multifunctional Tb-MOF for Highly Discriminative Sensing of Eu3+ /Dy3+ and as a Catalyst Support of Ag Nanoparticles
Autor: | Ya-Pan Wu, Jun Zhao, Qichun Zhang, Dongsheng Li, Wen-Wen Dong, Xue-Qian Wu, Guo-Wang Xu |
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Rok vydání: | 2017 |
Předmět: |
Materials science
Catalyst support Composite number Nanotechnology 4-Nitrophenol 02 engineering and technology General Chemistry Picolinic acid 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Fluorescence 0104 chemical sciences Catalysis Nanomaterials Biomaterials chemistry.chemical_compound Chemical engineering chemistry Dimethylformamide General Materials Science 0210 nano-technology Biotechnology |
Zdroj: | Small. 13:1602996 |
ISSN: | 1613-6810 |
Popis: | Exploring novel multifunctional rare earth materials is very important because these materials have fundamental interests, such as new structural facts and connecting modes, as well as potential technological applications, including optics, magnetic properties, sorption, and catalytic behaviors. Especially, employing these nanomaterials for sensing or catalytic reactions is still very challenging. Herein, a new superstable, anionic terbium-metal-organic-framework, [H2 N(CH3 )2 ][Tb(cppa)2 (H2 O)2 ], (China Three Gorges University (CTGU-1), H2 cppa = 5-(4-carboxyphenyl)picolinic acid), is successfully prepared, which can be used as a turn-on, highly-sensitive fluorescent sensor to detect Eu3+ and Dy3+ , with a detection limitation of 5 × 10-8 and 1 × 10-4 m in dimethylformamide, respectively. This result represents the first example of lanthanide-metal-organic-frameworks (Ln-MOF) that can be employed as a discriminative fluorescent probe to recognize Eu3+ and Dy3+ . In addition, through ion exchanging at room temperature, Ag(I) can be readily reduced in situ and embedded in the anionic framework, which leads to the formation of nanometal-particle@Ln-MOF composite with uniform size and distribution. The as-prepared Ag@CTGU-1 shows remarkable catalytic performance to reduce 4-nitrophenol, with a reduction rate constant κ as large as 2.57 × 10-2 s-1 ; almost the highest value among all reported noble-metal-nanoparticle@MOF composites. |
Databáze: | OpenAIRE |
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