Structure and thermal properties of a novel volatile bis(1,1,1-trifluoro-5,5-dimethyl-3-hexene-4-imino-2-onate) platinum(II) compound
| Autor: | P. A. Stabnikov, Anton I. Smolentsev, Natalya B. Morozova, Galina I. Zharkova, I. A. Baidina |
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| Rok vydání: | 2017 |
| Předmět: |
010405 organic chemistry
Chemistry Ligand Inorganic chemistry chemistry.chemical_element Crystallographic data 010402 general chemistry 01 natural sciences Medicinal chemistry Nitrogen Oxygen 0104 chemical sciences Inorganic Chemistry chemistry.chemical_compound Hexene Atom Materials Chemistry Physical and Theoretical Chemistry Platinum Coordination site |
| Zdroj: | Journal of Structural Chemistry. 58:970-974 |
| ISSN: | 1573-8779 0022-4766 |
| DOI: | 10.1134/s002247661705016x |
| Popis: | A novel volatile Pt(II)β-iminoketonate complex is synthesized. β-Aminovinylketone H(i-ptac) = [CF3–C(O)–CH=C(NH2)–C(CH3)3] is used as a ligand. The XRD method is used to determine the structures of the ligand and the complex. The crystallographic data for C16H22F6N2O2Pt are as follows: a = 10.0716(4) A, b = 10.9572(4) A, c = 9.6322(4) A, β = 110.9010(10)°, space group С2/m, Z = 2, R = 0.011. The platinum atom has a square planar coordination with two oxygen and two nitrogen atoms of two bidentately linked ketoiminate ligands in trans-position; the PtO2N2 coordination site is formed. |
| Databáze: | OpenAIRE |
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