The Molecular Structure of 3,5-Diethoxycarbonyl-2, 6-Dimethyl-1,4-Dihydropyridine. An X-Ray Study

Autor: Albert T. H. Lenstra, G. H. Petit, Frank C. Alderweireldt, Roger Dommisse
Rok vydání: 2010
Předmět:
Zdroj: Bulletin des Sociétés Chimiques Belges. 88:133-141
ISSN: 0037-9646
DOI: 10.1002/bscb.19790880303
Popis: The title compound crystallizes in P1, with a = 6.999 A, b = 7.491 A, c = 12.711 A, α = 91.1 °, β = 106.5 °, y = 90.1 ° and Z = 2. The structure was solved by rotation and translation search procedures and refined to a final R-value of 0.053. Excluding the hydrogen atoms, the molecule is planar. The compound is crystallized in such a way that a close packed layer structure is achieved. The influence of the packing of the molecules on the reduction of chloranil by 3,5-diethoxycarbonyl-2,6-dimethyl-1,4-dihydropyridine in solid state solutions is discussed.
Databáze: OpenAIRE
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