Electrochemical synthesis of some 1,2-dimethyl 1,2-disubstituted ethylenes

Autor:	Philippe Champagne, Roger N. Renaud
Rok vydání:	1979
Předmět:	chemistry.chemical_classification Diethyl fumarate Chemistry Anodic oxidation Organic Chemistry Inorganic chemistry General Chemistry Polymer Electrochemistry Catalysis chemistry.chemical_compound Monomer Polymer chemistry Sodium acetate Volume concentration
Zdroj:	Canadian Journal of Chemistry. 57:990-993
ISSN:	1480-3291 0008-4042
DOI:	10.1139/v79-163
Popis:	The anodic oxidation of sodium acetate in the presence of a series of 1,2-disubstituted ethylenes was performed in acetonitrile–water solution. Under low concentration of substrates, very good yields of the monomeric 1,2-dimethylated products were obtained. In the case of diethyl fumarate, an increase in concentration caused a decrease in the ratio of monomer to polymer when all other parameters were held constant.The stereoisomers of the products were separated and their physical properties are reported.
Databáze:	OpenAIRE
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