Coordination Chemistry of Isomeric Mixtures of Linked Di(phosphaguanidine) Compounds: A Spectroscopic and Crystallographic Study
| Autor: | Peter B. Hitchcock, Natalie E. Mansfield, and Anthony G. Avent, Martyn P. Coles |
|---|---|
| Rok vydání: | 2006 |
| Předmět: |
chemistry.chemical_classification
Ligand Organic Chemistry Diastereomer chemistry.chemical_element Nuclear magnetic resonance spectroscopy Coordination complex Inorganic Chemistry Metal Crystallography chemistry visual_art visual_art.visual_art_medium Chelation Physical and Theoretical Chemistry Platinum Bimetallic strip |
| Zdroj: | Organometallics. 25:2470-2474 |
| ISSN: | 1520-6041 0276-7333 |
| DOI: | 10.1021/om060014z |
| Popis: | Multinuclear NMR spectroscopy and X-ray diffraction techniques have been used to identify diastereomeric mixtures of rac- and meso-di(phosphaguanidine) compounds. A brief survey of their coordination chemistry has demonstrated the formation of N,N'-bound bimetallic aluminum species and monometallic platinum complexes in which the ligand chelates to the metal through the two phosphorus donor atoms. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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