Relay Cross Metathesis for the Ascent of the Terpenoids

Autor: Zhensheng Shi, Karim A. Bahou, Savage Gp, Braddock Dc, Adam G. Meyer
Rok vydání: 2019
Předmět:
DOI: 10.26434/chemrxiv.8267837.v1
Popis: We report the design and implementation of a relay cross metathesis (ReXM) reaction for the ascent of the terpenoids in an iterative protocol using naturally occurring terpenoid building blocks. The method is used for the synthesis of a diterpene-benzoate macrolide of biogenetic relevance to the bromophycolide family of natural products.
Databáze: OpenAIRE