Fischer–Tropsch Synthesis in the Presence of Catalysts Based on Unmodified Iron Ores
| Autor: | M. V. Kulikova, A. B. Kulikov, Mariya V. Chudakova, A. Yu. Krylova |
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| Rok vydání: | 2021 |
| Předmět: |
General Chemical Engineering
chemistry.chemical_element Fischer–Tropsch process 02 engineering and technology General Chemistry engineering.material 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences Catalysis Baddeleyite chemistry.chemical_compound Iron ore chemistry Yield (chemistry) Iron content engineering 0210 nano-technology Carbon Magnetite Nuclear chemistry |
| Zdroj: | Russian Journal of Applied Chemistry. 94:104-109 |
| ISSN: | 1608-3296 1070-4272 |
| DOI: | 10.1134/s1070427221010158 |
| Popis: | The use of commercial magnetite-type iron ore and of ferriferous quartzite type ore as catalysts for low-temperature Fischer–Tropsch synthesis is described. According to the results of chemical analysis, the ores mainly contained iron magnetite, carbon, and also baddeleyite (ZrO2 + HfO2) and hatchettolite (Ta2O5 + Nb2O5 + U3O8). The ore samples with the highest iron content (48–59%) and the lowest sulfur content (0.1% and less) showed activity in the Fischer–Tropsch synthesis without additional modification in the commercial form. The yield of liquid products in the synthesis performed on the most active samples of ore catalysts exceeded 100 g m–3 at the СО conversion of approximately 60%. The ore activity in the Fischer–Tropsch synthesis may be associated with the fact that these natural mineral formations contain oxides exerting a promoting effect when using the ores as catalysts. |
| Databáze: | OpenAIRE |
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