Negative ion mass spectra of metal complexes: Secondary electron capture and CS2 elimination from nickel (ii) dithiocarbamates

Autor:	I. K. Gregor, John L. Garnett, I. W. Fraser, K. J. Jessop
Rok vydání:	1975
Předmět:	Inorganic chemistry chemistry.chemical_element Biochemistry Secondary electrons Ion Metal Nickel chemistry visual_art Metastability visual_art.visual_art_medium Mass spectrum Molecular Medicine Instrumentation Spectroscopy
Zdroj:	Organic Mass Spectrometry. 10:69-73
ISSN:	1096-9888 0030-493X
DOI:	10.1002/oms.1210100111
Popis:	Negative ion mass spectra of series of bis-(N, N-dithiocarbamato)nickel(II) complexes of formula [NiS2C·NR1R2]2 (where·NR1R2 ·NEt2 ·NPr2, ·NBu2, pyrrolidinyl, piperidyl, morpholinyl, and ·NEtPh) have been obtained by secondary electron capture. Intense molecular anions are given for all compounds, with most fragments originating from these ions. Metastable data indicate that CS2 is eliminated from all molecular anions.
Databáze:	OpenAIRE
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