Radical cation salts based on BEDT-TTF and the paramagnetic anion [Cr(NCS)6]3−
| Autor: | F. Bérézovsky, Eugenio Coronado, José Ramón Galán-Mascarós, J. Sala Pala, Smail Triki, Carlos J. Gómez-García |
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| Rok vydání: | 1999 |
| Předmět: |
chemistry.chemical_classification
Stereochemistry Mechanical Engineering Metals and Alloys Salt (chemistry) Atmospheric temperature range Condensed Matter Physics Magnetic susceptibility Electronic Optical and Magnetic Materials Ion Paramagnetism Curie's law Crystallography chemistry Radical ion Mechanics of Materials Materials Chemistry Molecule |
| Zdroj: | Synthetic Metals. 102:1755-1756 |
| ISSN: | 0379-6779 |
| DOI: | 10.1016/s0379-6779(98)00403-2 |
| Popis: | A new radical cation salt formulated as (ET)5.5[Cr(NCS)6] (ET = BEDT-TTF = bis(ethylene)dithiotetrathiafulvalene) has been synthesised and characterised by X-ray diffraction and magnetic measurements. The structure shows the presence of alternating layers of the ET units and mixed layers of anions and an isolated ET molecule. The magnetic susceptibility data in the temperature range 2–300 K show a Curie law with C = 1.771 cm3.K.mol−1 and Nα = 1.20.10−5 cm3.mol−1, in agreement with the presence of isolated Cr(III) without any contribution from the organic part. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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