Iodine-Promoted Synthesis of 4-Aryl-2-(arylsulfonyl)quinolones by Desulfurative C–S Cross-Coupling Reaction of Quinoline-2-thiones with Sodium Sulfinates

Autor:	Xi-Chun Wang, Guo-Chao Yang, Zheng-Jun Quan
Rok vydání:	2020
Předmět:	010405 organic chemistry Sodium Aryl Organic Chemistry Quinoline chemistry.chemical_element Substrate (chemistry) 010402 general chemistry Iodine 01 natural sciences Medicinal chemistry Sulfur Coupling reaction 0104 chemical sciences chemistry.chemical_compound chemistry Bond cleavage
Zdroj:	Synlett. 31:1527-1531
ISSN:	1437-2096 0936-5214
DOI:	10.1055/s-0040-1706868
Popis:	An iodine-induced sulfonylation of quinoline-2-thiones with sodium arenesulfinates as sulfur sources for the synthesis of 4-aryl-2-(arylsulfonyl)quinoline derivatives is described. The 4-aryl-2-(arylsulfonyl)quinoline derivatives can be obtained in a moderate to good yields. This C–S bond cleavage and C–S cross-coupling proceeds in the absence of a metal under inexpensive and nontoxic conditions and it displays a broad substrate scope.
Databáze:	OpenAIRE
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