The synthesis, structure, and magnetic properties of a novel copper(II) cluster with H-bonding directed 3D-structure comprised of interconnected double-stranded ladders

Autor:	Neil Patel, Santokh S. Tandon, Laurence K. Thompson, Scott D. Bunge
Rok vydání:	2009
Předmět:	Tris Chemistry Hydrogen bond Stereochemistry chemistry.chemical_element Copper Inorganic Chemistry chemistry.chemical_compound Crystallography Materials Chemistry Cluster (physics) Sodium azide Hydroxymethyl Physical and Theoretical Chemistry Double stranded
Zdroj:	Inorganic Chemistry Communications. 12:1077-1080
ISSN:	1387-7003
Popis:	Reaction between 2,6-diformyl-4-methylphenol (DFMP) and tris(hydroxymethyl)aminomethane (THMAM) with copper(II) acetate and sodium azide formed the antiferromagnetically coupled, polymeric copper(II) coordination cluster {[(H5L)Cu2(μ-N3)]2[Cu(N3)4]·2CH3OH}n (1), with a novel double-stranded ladder like structure in which [Cu(N3)4]2− anions link single-chains comprised of dinuclear subunits, forming a 3D-structure of interconnected ladders through H-bonding. The 3D-structure is the result of coordinatively driven and hydrogen-bonding directed self-assembly.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::a15b34786b260f00302e60ddd2bbd101 https://doi.org/10.1016/j.inoche.2009.08.028 Zobrazit plný text záznamu Full Text from ScienceDirect