Instrumental analysis for trace elements present in Chicago area surface air

Autor: D. M. Hattori, J. R. Kline, S.S. Brar, D. M. Nelson, Gustafson Pf, Carl E. Moore, Eugene L. Kanabrocki
Rok vydání: 1970
Předmět:
Zdroj: Journal of Geophysical Research. 75:2939-2945
ISSN: 0148-0227
DOI: 10.1029/jc075i015p02939
Popis: On April 4, 1968, surface air particulates were collected on cellulose fiber filters simultaneously at twenty-two different locations throughout the Chicago metropolitan area. A 1-cm2 portion of each filter was irradiated with thermal neutrons in Argonne National Laboratory's CP-5 research reactor. The neutron-induced nuclides were analyzed by γ-ray spectrometry with 10.2 cm × 10.2 cm (4 in. × 4 in.) and 7.6 cm × 7.6 cm (3 in. × 3 in.) cylindrical NaI(Tl) crystals and a 400-channel analyzer. By varying the neutron flux and the time of irradiation, we were able to detect by purely instrumental means twenty trace elements in surface air. The following elements, listed in decreasing order of concentration, were present: iron, chlorine, aluminum, zinc, manganese, sodium, bromine, vanadium, chromium, antimony, mercury, selenium, cerium, silver, cobalt, lanthanum, scandium, cesium, and europium. The average concentrations varied from 2400 to 0.12 ng/m3 air. Calcium concentrations in air were not quantitated.
Databáze: OpenAIRE