Extended X- ray absorption fine structure study at the K-edge of copper in mixed ligand complexes having benzimidazole as one of the ligands

Autor:	V K Hinge, Jagdish Prasad, N. Nitin Nair, K Srivastava, Vikram Singh Verma, S. K. Joshi, B. D. Shrivastava
Rok vydání:	2014
Předmět:	History Extended X-ray absorption fine structure Chemistry chemistry.chemical_element Copper Spectral line Computer Science Applications Education Bond length Crystal symbols.namesake Crystallography Fourier transform K-edge symbols Absorption (chemistry)
Zdroj:	Journal of Physics: Conference Series. 534:012024
ISSN:	1742-6596 1742-6588
DOI:	10.1088/1742-6596/534/1/012024
Popis:	Extended X-ray absorption fine structure (EXAFS) spectra have been studied at the K-edge of copper in some of its biologically important complexes, viz., [Cu(BzImH)4X2] and [Cu(BzIm)2], where X= Cl, Br, 1/2SO4, ClO4, NO3, and BzIm = Benzimidazolato anion. The spectra have been recorded using a bent crystal 0.4 m Cauchois-type transmission spectrograph. The positions of EXAFS maxima and minima have been used to determine the bond lengths in the complexes with the help of three different methods, namely, Levy's, Lytle's and Lytle, Sayers and Stern's (L.S.S.) methods. The phase uncorrected bond lengths have also been determined from Fourier transforms of the experimental spectra. The results obtained from these methods have been discussed and it has been found that the results obtained by L.S.S. method are comparable with the results obtained by Fourier transformation method and that these two methods give phase uncorrected bond lengths.
Databáze:	OpenAIRE
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