Possibilities of Decreasing Absorption of Water in Ion-Exchanger Catalysts
Autor: | Zdeněk Prokop, Karel Jeřábek |
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Rok vydání: | 1998 |
Předmět: | |
Zdroj: | Collection of Czechoslovak Chemical Communications. 63:1907-1914 |
ISSN: | 1212-6950 0010-0765 |
DOI: | 10.1135/cccc19981907 |
Popis: | Possibilities of decreasing the ability of strong-acid ion-exchanger catalysts to retain water were investigated in a case study of bisphenol A synthesis for to diminish effects of water as reaction product on the kinetics of the catalyzed reaction. It was found that partial thermal desulfonation or neutralization of about 30-40% acid groups with 2-aminoethanethiol can produce catalysts which exhibit, in the presence of technologically significant concentration of water, a higher activity in bisphenol A synthesis than conventional ion-exchanger catalysts. |
Databáze: | OpenAIRE |
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