Chlorine nuclear quadrupole coupling in platinum and palladium dichlorides

Autor:	Ronald Nyholm, W. van Bronswyk
Rok vydání:	1968
Předmět:	Coupling constant Coupling Inorganic chemistry chemistry.chemical_element Electron Inorganic Chemistry Molecular geometry chemistry Quadrupole Physical chemistry Physical and Theoretical Chemistry Platinum Nuclear quadrupole resonance Palladium
Zdroj:	Journal of the Chemical Society A: Inorganic, Physical, Theoretical. :2084
ISSN:	0022-4944
DOI:	10.1039/j19680002084
Popis:	Nuclear quadrupole resonance studies confirm the existence of α-PdCl2, β-PdCl2, and β-PtCl2, and show that whilst the β-PtCl2 structure is distorted the β-PdCl2 structure is regular. The magnitudes of the coupling constants show that the α- and β-structures have nearly identical electron distributions, all differences being due, presumably, to changes in the metal–chlorine–metal bond angle.
Databáze:	OpenAIRE
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