The use of intermolecular potential functions in fitting pressure induced spectra

Autor:	Robert W. Boese, D. Goorvitch, P. M. Silvaggio
Rok vydání:	1981
Předmět:	Radiation Materials science Absorption spectroscopy Intermolecular force Van der Waals strain Molecular physics Atomic and Molecular Physics and Optics Spectral line symbols.namesake Intermolecular potential symbols Van der Waals radius Angular dependence van der Waals force Spectroscopy
Zdroj:	Journal of Quantitative Spectroscopy and Radiative Transfer. 26:277-279
ISSN:	0022-4073
Popis:	An example is presented which demonstrates the importance of using physically realistic derivatives of the intermolecular potential when fitting pressure-induced spectra. The use of nonrealistic derivatives may mask second-order temperature effects in the theory. As the temperature decreases, the intermolecular potential may have an important angular dependence.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::a10f2e110877df5665b7bf760fc3e039 https://doi.org/10.1016/0022-4073(81)90121-7 Zobrazit plný text záznamu