Effects of substitution of Dy for Nd on the structural and magnetic properties of Nd3−xDyxFe27.5Mo1.5 (0.3⩽x⩽1.8)

Autor: Y.J. Xue, J.H. Li, Z.B. Hu, Xiangfeng Liu, Xiang-Biao Li, Jie Peng, D.F. Chen, Han Shiji, Jianguo Lv
Rok vydání: 2005
Předmět:
Zdroj: Physica B: Condensed Matter. 367:275-281
ISSN: 0921-4526
DOI: 10.1016/j.physb.2005.06.028
Popis: A series of Nd 3− x Dy x Fe 27.5 Mo 1.5 (0.3⩽ x ⩽1.8) intermetallic compounds were prepared. Their structural properties have been investigated using powder X-ray diffraction and their magnetic properties have been studied by a vibrating sample magnetometer (VSM). Rietveld refinement of the X-ray patterns shows that the lattice constants a , b , c and the unit cell volume V are decreased by the substitution of Dy for Nd. Mo prefers to occupy 4i 1 , 4i 2 and 4 g sites due to the size and thermodynamic effects. The Curie temperatures T C of the 3:29 phases in all samples obtained by TMA measurements do not show remarkable changes. However, the saturation magnetizations of the samples decrease monotonically with more Nd replaced by Dy in compounds.
Databáze: OpenAIRE