Diastereoselective hydrogenation of methyl esters of trifluoroacetyldehydrophenylanalyl dipeptides and trifluoroacetyldehydrovalyl dipeptides

Autor:	E. I. Klabunovskii, G. V. Chel'tsova-Bebutova, E. I. Karpeiskaya, Sh. G. Bitiev
Rok vydání:	1987
Předmět:	chemistry.chemical_classification Residue (chemistry) chemistry Stereochemistry Organic chemistry Stereoselectivity General Chemistry Proline Amino acid
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 36:1472-1475
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf01557526
Popis:	The stereoselectivity of hydrogenation of methyl esters of N-trifluoroacetyl dehydrodipeptides on a Ni-catalyst was determined by the structure of the C-terminal residue and the prochiral center. The S-configuration of the C-terminal amino acid leads to the formation of the R-configuration of a new center. The proline residue has the highest induction.
Databáze:	OpenAIRE
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