Modulation of charge carrier pathways in CdS nanospheres by integrating MoS2 and Ni2P for improved migration and separation toward enhanced photocatalytic hydrogen evolution
| Autor: | Jiha Choi, D. Amaranatha Reddy, Tae Kyu Kim, Sangyeob Hong, Noh Soo Han, Jae Kyu Song, Seonghyun Jeong, D. Praveen Kumar |
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| Rok vydání: | 2017 |
| Předmět: |
Photocurrent
Nanocomposite Photoluminescence Materials science business.industry Nanotechnology 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Catalysis 0104 chemical sciences Semiconductor Photocatalysis Quantum efficiency Charge carrier 0210 nano-technology business |
| Zdroj: | Catalysis Science & Technology. 7:641-649 |
| ISSN: | 2044-4761 2044-4753 |
| Popis: | The photocatalytic hydrogen evolution reaction using semiconductor nanostructures has received considerable attention in tackling energy and pollution problems. Although several semiconductor photocatalysts have been developed, materials satisfactory in all aspects (e.g., economical and eco-friendly with high efficiency) are still to be developed. Herein, a new and efficient noble-metal-free CdS/MoS2@Ni2P ternary nanohybrid photocatalyst is prepared using a combined hydrothermal and metal–organic framework template strategy. The designed nanostructures show an appealing hydrogen evolution rate, which is 69.29-fold higher than the bare CdS nanostructures and almost 6-fold higher than the CdS–Pt nanocomposites, with an apparent quantum efficiency of 24.4%. Furthermore, the rate enhancement factor of photocatalytic hydrogen evolution in the presence of MoS2 and Ni2P on CdS is much larger than that of several cocatalyst-modified CdS nanostructures reported earlier. The enhanced photocatalytic hydrogen evolution rate is attributed to better migration and separation efficiency in CdS/MoS2@Ni2P than bare CdS, which is supported by photoluminescence, dynamics, photocurrent, and impedance studies. We anticipate that the work presented here may open up new insights for the utilization of low-cost CdS/MoS2@Ni2P hybrid nanostructures as a substitute for noble metals for effective photocatalytic hydrogen evolution. |
| Databáze: | OpenAIRE |
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