2-Acetyl-substituted polyfluorinated ?-keto esters in reaction with amines
Autor: | V. M. Krokhalev, K. I. Pashkevich, Viktor I. Saloutin |
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Rok vydání: | 1988 |
Předmět: | |
Zdroj: | Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 37:1202-1206 |
ISSN: | 1573-9171 0568-5230 |
Popis: | 1. By the action of ammonia, ethylenediamine, o-phenylenediamine, 2-acetyl-substituted polyfluorinated Β-keto esters undergo an “acidic” splitting with the elimination of the polyfluoroacyl group in the form of the corresponding derivatives. 2. Besides the splitting, 2-acetyl-substituted polyfluorinated Β-keto esters reactwith hydrazine and phenylhydrazine at the Β-diketonic” fragment to form substituted pyrazoles. |
Databáze: | OpenAIRE |
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