2-Acetyl-substituted polyfluorinated ?-keto esters in reaction with amines

Autor: V. M. Krokhalev, K. I. Pashkevich, Viktor I. Saloutin
Rok vydání: 1988
Předmět:
Zdroj: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 37:1202-1206
ISSN: 1573-9171
0568-5230
Popis: 1. By the action of ammonia, ethylenediamine, o-phenylenediamine, 2-acetyl-substituted polyfluorinated Β-keto esters undergo an “acidic” splitting with the elimination of the polyfluoroacyl group in the form of the corresponding derivatives. 2. Besides the splitting, 2-acetyl-substituted polyfluorinated Β-keto esters reactwith hydrazine and phenylhydrazine at the Β-diketonic” fragment to form substituted pyrazoles.
Databáze: OpenAIRE