Atomic Dimensions from the Coefficients of Compressibility and Thermal Expansion

Autor: G. F. Djang
Rok vydání: 1936
Předmět:
Zdroj: The Journal of Chemical Physics. 4:530-532
ISSN: 1089-7690
0021-9606
DOI: 10.1063/1.1749897
Popis: Starting from the equation of state p—K(V—V0)/V0 = RT/V—V0, the relation αa/β = R/(V—V0) is derived, where V0 is identified with the actual volume occupied by one mole of atoms or molecules. Values of the radii of atoms for different elements are calculated from this relation and compared to the values obtained from crystal analysis. Possibility of using the relation αa/β = R/(V—V0) to estimate molecular dimensions in the liquid state is also referred to.
Databáze: OpenAIRE