Atomic Dimensions from the Coefficients of Compressibility and Thermal Expansion
Autor: | G. F. Djang |
---|---|
Rok vydání: | 1936 |
Předmět: | |
Zdroj: | The Journal of Chemical Physics. 4:530-532 |
ISSN: | 1089-7690 0021-9606 |
DOI: | 10.1063/1.1749897 |
Popis: | Starting from the equation of state p—K(V—V0)/V0 = RT/V—V0, the relation αa/β = R/(V—V0) is derived, where V0 is identified with the actual volume occupied by one mole of atoms or molecules. Values of the radii of atoms for different elements are calculated from this relation and compared to the values obtained from crystal analysis. Possibility of using the relation αa/β = R/(V—V0) to estimate molecular dimensions in the liquid state is also referred to. |
Databáze: | OpenAIRE |
Externí odkaz: |