Reaction of ferrocenium ion with secondary phosphines: replacement of cyclopentadienyl ligand rather than its C—H functionalization

Autor:	V. V. Krivykh, Aleksandr A. Chamkin, Kamil I. Utegenov, Nikolai A. Ustynyuk, N. A. Shtel´tser, F. M. Dolgushin
Rok vydání:	2019
Předmět:	Cyclopentadienyl complex 010405 organic chemistry Ligand Chemistry Polymer chemistry Surface modification General Chemistry 010402 general chemistry Ring (chemistry) 01 natural sciences 0104 chemical sciences Ion
Zdroj:	Russian Chemical Bulletin. 68:1380-1383
ISSN:	1573-9171 1066-5285
Popis:	The reactions of ferrocenium salts with secondary phosphines Ph2PH, Cy2PH, and Et2PH proceed as replacement of the cyclopentadienyl ring to afford half-sandwich complexes [C5H5Fe(R2PH)3](X) (X = PF6, BF4) rather than ferrocenylphosphonium salts [C5H5FeC5H4— (PHR2)](X).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::a0c5ac24fad37e81a8103bfebe9e495e https://doi.org/10.1007/s11172-019-2565-5 Zobrazit plný text záznamu Full text from SpringerLink