Batch Reactive Distillation in Bromodifluoroacetic Acid Synthesis Technology

Autor:	S. Ya. Kvashnin, E. V. Lupachev, V. A. Lotkhov, A. V. Polkovnichenko, N. N. Kulov
Rok vydání:	2019
Předmět:	Chemistry General Chemical Engineering 0211 other engineering and technologies Sulfuric acid 02 engineering and technology General Chemistry Transesterification Catalytic distillation Catalysis chemistry.chemical_compound 020401 chemical engineering Scientific method Yield (chemistry) Reactive distillation Trifluoroacetic acid 0204 chemical engineering 021102 mining & metallurgy Nuclear chemistry
Zdroj:	Theoretical Foundations of Chemical Engineering. 53:1-12
ISSN:	1608-3431 0040-5795
DOI:	10.1134/s004057951901010x
Popis:	A catalytic distillation process reacting in a column bottom was experimentally studied for the transesterification of methyl and ethyl esters of bromodifluoroacetic acid with trifluoroacetic acid. Sulfuric acid was used as a catalyst. Experiments were performed at different column bottom heat duties. As a result of the experiments, we had bromodifluoroacetic acid with a purity above 97.0 mol % at a product yield of 87.4%.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::a0b6804deb7ccf1af281f19315622324 https://doi.org/10.1134/s004057951901010x Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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