A kinetic investigation of the thermal rearrangement of N-pyridino-2-vinyl-aziridines

Autor:	R. Jammar, Hubert Figeys
Rok vydání:	1981
Předmět:	chemistry.chemical_compound Reaction rate constant Chemistry Organic Chemistry Drug Discovery Thermal Substituent Kinetic energy Photochemistry Biochemistry Isomerization
Zdroj:	Tetrahedron Letters. 22:637-640
ISSN:	0040-4039
DOI:	10.1016/s0040-4039(01)92510-9
Popis:	The first-order rate constants of the thermal rearrangement of several N-pyridino-2-vinyl-aziridines into the corresponding pyrido-azepines have been determined. Substituent effects on this isomerization were found to be completely analogous to the related benzenic O-Claisen rearrangement.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::a0afea7ac07ba7e5813993a537aedfd2 https://doi.org/10.1016/s0040-4039(01)92510-9 Zobrazit plný text záznamu