Dilithium Tetrachlorocuprate(II) Catalyzed Oxidative Homocoupling of Functionalized Grignard Reagents

Autor:	Qiu-Peng Hu, Si-Kai Hua, Jiangmeng Ren, Bu-Bing Zeng
Rok vydání:	2013
Předmět:	chemistry.chemical_classification Chemistry Metalation Aryl Organic Chemistry Halide Oxidative phosphorylation Dilithium tetrachlorocuprate Catalysis chemistry.chemical_compound Reagent Polymer chemistry Alkyl
Zdroj:	Synthesis. 45:518-526
ISSN:	1437-210X 0039-7881
DOI:	10.1055/s-0032-1316841
Popis:	An efficient procedure is described for the oxidative homocoupling of functionalized Grignard reagents using a catalytic amount of dilithium tetrachlorocuprate(II) (CuLi2Cl4) in the presence of pure oxygen gas. This method is applied successfully to a variety of aryl, heteroaryl, alkyl, alkenyl and alkynyl halides, which are converted into the corresponding homocoupled products in good to excellent yields.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::a09053e8d56877286f730fda3263a81d https://doi.org/10.1055/s-0032-1316841 Zobrazit plný text záznamu