Defect distribution in ZnO thin films grown on a-plane sapphire substrates by catalytic-reaction-assisted chemical vapor deposition

Autor: Kanji Yasui, Taro Saito, Ariyuki Kato
Rok vydání: 2021
Předmět:
Zdroj: Journal of Crystal Growth. 570:126206
ISSN: 0022-0248
Popis: This work examined the crystalline structure of a ZnO thin film grown on an a-plane sapphire substrate through a reaction between dimethylzinc and high-energy H2O molecules produced by the Pt-catalysed reaction of gaseous H2 and O2. The dislocation distribution in a ZnO film with a thickness of 5 μm grown on an a-plane sapphire substrate was observed using cross-sectional dual-beam transmission electron microscopy, and the dislocation density was evaluated by Ham’s method. A much higher dislocation density was found at the film-substrate interface than at the film surface. The influences of film thickness on the full width at half maximum of the X-ray diffraction rocking curve and on the electron mobility are both attributed to this localized high density of defects.
Databáze: OpenAIRE