Chlorine-Dioxide as an Electron Transfer Oxidant of Olefins

Autor:	E. Choshen, Shalom Sarel, Ch. Rav-Acha
Rok vydání:	1988
Předmět:	Hydrolysis Olefin fiber Chlorine dioxide chemistry.chemical_compound Electron transfer Chemistry Ionization Yield (chemistry) Ionization energy Photochemistry Ion
Zdroj:	Organic Free Radicals ISBN: 9783540501299
DOI:	10.1007/978-3-642-73963-7_89
Popis:	Kinetic and product studies of chlorine-dioxide oxidation of olefins, ranging in their ionization potentials from 9.64±0.3 to 8.0 eV have shown that at the rate-determing stage, the reaction involved the abstraction of an electron from the olefin to yield the anion ClO2 ∸ with generation of the corresponding cation radical ****. The products emerging from the oxidation in H2O were suggested to arise from an hydrolysis reaction of a postulated cyclic-intermediate.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::a06fa0f5c518d7c0f352f4436a0646e0 https://doi.org/10.1007/978-3-642-73963-7_89 Zobrazit plný text záznamu