Autor: |
W. K. Busfield, San H. Thang, D. I. Grice, Ian D. Jenkins |
Rok vydání: |
2010 |
Předmět: |
|
Zdroj: |
ChemInform. 23 |
ISSN: |
0931-7597 |
Popis: |
The pattern of reactions occurring between t- butoxy radicals and a number of cyclic alkenes has been investigated by the nitroxide radical-trapping technique. The major reaction pathway is allylic abstraction unless this position is at a bridgehead as in norbornene where the major pathway is radical addition. The technique is sufficiently sensitive to identify minor reaction pathways of non-allylic substitution and radical addition when in the presence of extensive allylic substitution. Some stereoselective effects are also detected. |
Databáze: |
OpenAIRE |
Externí odkaz: |
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