ChemInform Abstract: Reaction of t-Butoxy Radicals with Cyclic Alkenes Studied by the Nitroxide Radical-Trapping Technique

Autor:	W. K. Busfield, San H. Thang, D. I. Grice, Ian D. Jenkins
Rok vydání:	2010
Předmět:	Allylic rearrangement Nitroxide mediated radical polymerization Chemistry organic chemicals Radical food and beverages Nanotechnology General Medicine Trapping Photochemistry Nitroxide radical Cyclic Alkenes chemistry.chemical_compound Stereoselectivity Norbornene
Zdroj:	ChemInform. 23
ISSN:	0931-7597
Popis:	The pattern of reactions occurring between t- butoxy radicals and a number of cyclic alkenes has been investigated by the nitroxide radical-trapping technique. The major reaction pathway is allylic abstraction unless this position is at a bridgehead as in norbornene where the major pathway is radical addition. The technique is sufficiently sensitive to identify minor reaction pathways of non-allylic substitution and radical addition when in the presence of extensive allylic substitution. Some stereoselective effects are also detected.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::a065480a93fffa868344dbd1357a2a1d https://doi.org/10.1002/chin.199203116 Zobrazit plný text záznamu Plný text