Mono- and diisothiocyanophosphoric acid esters and their derivatives

Autor:	L. N. Levkova, P. I. Alimov
Rok vydání:	1964
Předmět:	Diethanolamine Aminobutyrate chemistry.chemical_element General Chemistry Medicinal chemistry Ethyl glycinate chemistry.chemical_compound chemistry Thiourea Potassium thiocyanate Yield (chemistry) Phosphorus atom Chlorine Organic chemistry
Zdroj:	Bulletin of the Academy of Sciences, USSR Division of Chemical Science. 13:172-174
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf01179595
Popis:	1. On reacting ethyl-, propyl-, butyl- and isobutylphosphoric acid dichlorides with potassium thiocyanate the corresponding diisothiocyanophosphoric acid esters were obtained in yields of 35 to 55% of theoretical. 2. On reacting ethyl diisothiocyanophosphate with ethyl glycinate, ethyl -aminobutyrate and p-chloroaniline and butyl diisothiocyanophosphate with p-chloroaniline the corresponding derivatives with two substituted thiourea residues bonded directly to a phosphorus atom were obtained. 3. On reacting diethyl isothiocyanophosphate with ethyl glycinate, 2-amino-4-methylthiazole, N-phenylglycine and diethanolamine the corresponding di-N-substituted thioureas were obtained. 4. On reacting diethyl isothiocyanophosphate with chlorine dichloromethyleneimine-N-diethylphosphate was obtained in high yield.
Databáze:	OpenAIRE
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