ChemInform Abstract: Reversible Friedel-Crafts Acylations of 3-Alkyl-1-(phenylsulfonyl) pyrroles: Application to the Synthesis of an Ant Trail Pheromone

Autor:	P. G. Seybold, Jeffrey A. Schreier, James H. Cook, Dong Xiao, Daniel M. Ketcha
Rok vydání:	2010
Předmět:	chemistry.chemical_classification Stereochemistry education food and beverages General Medicine Trail pheromone behavioral disciplines and activities Pyrrole derivatives ANT chemistry Sex pheromone Organic chemistry Friedel–Crafts reaction health care economics and organizations Alkyl
Zdroj:	ChemInform. 27
ISSN:	0931-7597
DOI:	10.1002/chin.199625113
Popis:	Friedel-Crafts acylations of 3-alkyl-1-(phenylsulfonyl)pyrroles appear to be kinetically favored at the adjacent C-2 position but rearrangement to the C-5 position can occur after prolonged reaction times. This reversible Friedel-Crafts methodology has been employed for the synthesis of the ant trail pheromone, methyl 4-methylpyrrole-2-carboxylate.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::a03f3f4b3245741540f2fb2041c8b447 https://doi.org/10.1002/chin.199625113 Zobrazit plný text záznamu Plný text