Behaviour of some Th(IV) and U(VI) compounds in disulphuric acid

Autor:	K. C. Malhotra, S.C. Chaudhry
Rok vydání:	1981
Předmět:	Polymers and Plastics Monobasic acid Inorganic chemistry Oxide Electrolyte Uranyl Chloride chemistry.chemical_compound chemistry Nitrate Materials Chemistry medicine Uranyl chloride medicine.drug
Zdroj:	Journal of Inorganic and Nuclear Chemistry. 43:1547-1550
ISSN:	0022-1902
DOI:	10.1016/0022-1902(81)80334-x
Popis:	Th(IV) oxide, -nitrate, -acetate, -sulphate and chloride form H 2 [Th(HSO 4 ) 6 ] when dissolved in disulphuric acid, which behaves as monobasic acid of the system. At higher concentration, H 2 [Th(HSO 4 ) 6 ] is slightly polymerised. U(VI) oxide, uranyl sulphate, uranyl carboxylates and uranyl chloride form UO 2 (HSO 4 ) 2 when dissolved in disulphuric acid which polymerises at higher concentration. U(VI) chloride gets solvolysed to form the acids H[U(HSO 4 ) 7 ] or H 2 [U(HSO 4 ) 8 ] which behave as non electrolytes in disulphuric acid.
Databáze:	OpenAIRE
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