A stereocontrolled total synthesis of optically active (R,R)-phytol

Autor: Tamotsu Fujisawa, Toshio Sato, Kazuo Ohashi, Tatsuo Kawara
Rok vydání: 1981
Předmět:
Zdroj: Tetrahedron Letters. 22:4823-4826
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)92354-8
Popis: A stereospecific synthesis of (R,R)-phytol uith highly stereochemioal purity in both absolute and geometrical aonfigurations uas achieved by utilizing the SNZ type ring-opening reaction of (R)-β-methyl-β-propiolactone, and the SNZ′ type ring-opening reaction of isopropenyl oxirane, from (R)-pulegone as a starting material.
Databáze: OpenAIRE