A stereocontrolled total synthesis of optically active (R,R)-phytol
Autor: | Tamotsu Fujisawa, Toshio Sato, Kazuo Ohashi, Tatsuo Kawara |
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Rok vydání: | 1981 |
Předmět: | |
Zdroj: | Tetrahedron Letters. 22:4823-4826 |
ISSN: | 0040-4039 |
DOI: | 10.1016/s0040-4039(01)92354-8 |
Popis: | A stereospecific synthesis of (R,R)-phytol uith highly stereochemioal purity in both absolute and geometrical aonfigurations uas achieved by utilizing the SNZ type ring-opening reaction of (R)-β-methyl-β-propiolactone, and the SNZ′ type ring-opening reaction of isopropenyl oxirane, from (R)-pulegone as a starting material. |
Databáze: | OpenAIRE |
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