Monte Carlo-studium der ireversiblen terpolymerisation: Das modell und anwendungen

Autor:	O. Dragomir, Holban, I. Moţoc, I. Muşcutariu
Rok vydání:	1980
Předmět:	chemistry.chemical_compound Chemistry Methacrylonitrile Monte Carlo method Polymer chemistry Copolymer Physical chemistry Maleic anhydride Methyl methacrylate Methyl acrylate Ternary operation Styrene
Zdroj:	Journal of Polymer Science: Polymer Chemistry Edition. 18:1565-1575
ISSN:	1542-9369 0360-6376
DOI:	10.1002/pol.1980.170180514
Popis:	The Monte Carlo model of the ternary irreversible copolymerization is presented. The computer program MEMoRY-4, which implements the described model, is used to study the methyl methacrylate/methyl acrylate/maleic anhydride, butadiene/styrene/2-methyl-5-vinylpyridine, and styrene/methacrylonitrile/α-methyl styrene terpolymers. One discusses the problem of transferability of reactivity ratios determined for binary copolymerizations to the ternary ones. It can be concluded that the transferability is not assured, but using only composition data it is difficult to achieve a safe conclusion (Fisher statistics).
Databáze:	OpenAIRE
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