Photodissociation and photochemistry of V+(H2O)n, n = 1–4, in the 360–680 nm region

Autor:	Ina Herber, Christian van der Linde, Doreen Schütze, Martin K. Beyer, O. Petru Balaj, Björn Scharfschwerdt
Rok vydání:	2012
Předmět:	Full width at half maximum Solvation shell Materials science Physics and Astronomy (miscellaneous) Photodissociation Mass spectrum Cyclotron resonance General Physics and Astronomy Density functional theory Photochemistry Spectral line Fourier transform ion cyclotron resonance
Zdroj:	Low Temperature Physics. 38:717-722
ISSN:	1090-6517 1063-777X
Popis:	Photodissociation and photochemistry of V+(H2O)n, n = 1–4, was studied in 360–680 nm region using a Fourier transform ion cyclotron resonance mass spectrometer. The light of a high pressure mercury arc lamp was filtered using a set of bandpass filters with the center wavelengths from 360 to 680 nm in steps of 20 nm. The bandwidth of the filters, defined as full width at half maximum, was 10 nm. Photodissociation channels were attributed to loss of water molecules as well as atomic or molecular hydrogen, possibly accompanied by loss of water molecules. The most intense absorptions were red-shifted with increasing hydration. Theoretical spectra were calculated using time-dependent density functional theory. Calculations reproduced all the features of the experimental spectra, including the red shift with increasing hydration shell and the overall pattern of strong and weak absorption peaks.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::9fe405baf7d74fd59185f05f3060fc86 https://doi.org/10.1063/1.4743415 Zobrazit plný text záznamu