Monolithic poly(butyl methacrylate-ethylene dimethacrylate-methacrylic acid) column for capillary electrochromatography

Autor:	Kaname Ohyama, Naotaka Kuroda, Daisuke Horiguchi, Naoya Kishikawa
Rok vydání:	2011
Předmět:	geography Capillary electrochromatography Reproducibility geography.geographical_feature_category Monolithic HPLC column Chromatography Chemistry Filtration and Separation Repeatability Analytical Chemistry Butyl methacrylate chemistry.chemical_compound Methacrylic acid Monolith Ethylene dimethacrylate
Zdroj:	Journal of Separation Science. 34:2279-2283
ISSN:	1615-9306
DOI:	10.1002/jssc.201100198
Popis:	A butyl methacrylate–ethylene dimethacrylate–methacrylic acid (MAA) monolithic column was prepared for capillary electrochromatography. The effect of MAA weight percentage on the EOF mobility and column efficiency was studied. BMA–EDMA–MAA monolith with higher content of MAA provided higher EOF mobility as well as higher efficiency. The effect of mobile-phase composition and buffer pH was also investigated. The monolithic columns exhibited a good repeatability and reproducibility of column preparation with relative standard deviation values below 16% in the studied chromatographic parameters.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::9fdb1cd6c5c6587118df1abc31bd9f6f https://doi.org/10.1002/jssc.201100198 Zobrazit plný text záznamu Plný text