Mesomorphic phase transitions of tetraphenylporphyrins with four long aliphatic chains

Autor:	Kazuchika Ohta, Masaru Miya, Akira Nagata, Shigekazu Kusabayashi, Yo Shimizu, Iwao Yamamoto
Rok vydání:	1993
Předmět:	chemistry.chemical_classification Phase transition Materials science General Chemistry Condensed Matter Physics Metal Crystallography chemistry Liquid crystal visual_art Alkoxy group visual_art.visual_art_medium Organic chemistry General Materials Science Lamellar structure Alkyl
Zdroj:	Liquid Crystals. 14:795-805
ISSN:	1366-5855 0267-8292
Popis:	Studies of 5,10,15,20-tetrakis(4-n-alkylphenyl)porphyrins revealed that the homologues with longer alkyl chains than hexyl were mesomorphic, in contrast to the non-mesomorphic alkoxy derivatives. Metal complexes (Co, Ni, Cu, Zn, and Pd) of the dodecyl derivative were also shown to exhibit mesophases. These mesophases were assigned as discotic lamellar (DL) phases by X-ray diffraction studies.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::9fd83bb88a42e23613cf4b42d8232cf5 https://doi.org/10.1080/02678299308027756 Zobrazit plný text záznamu